Mössbauer spectroscopy of frozen solutions

Fülszöveg

The hook slarts out by reviewing the physical background and technical details of Mössbauer spectroscopy. v.
Although the Mössbauer eíTect can occur only in solids the aim here is lo demonstrate how lo apply Mössbauer spectroscopy lo the investigation of the chemical structure of solutions.
Solutions can be brought loa frozen stale and in this stale if they include Mössbauer-active atoms il is possible to record Mössbauer spectra. The process of freezing can be carricd out in a way lhat the ice formed preserves the most significant chemical features of the solutions. In that ease the Mössbauer method can serve as a rich source of information on the geometrical, chemical and magnetic structure of solulions.
The Mössbauer spectra of solulions and liquids can also be recorded al room temperature if they are diffunded in "thirsty glass" with a pore diameter of 4 nm. This recently developed measuring technique and ihe related principles are also discussed in this volume.
The... Tovább

Fülszöveg

The hook slarts out by reviewing the physical background and technical details of Mössbauer spectroscopy. v.
Although the Mössbauer eíTect can occur only in solids the aim here is lo demonstrate how lo apply Mössbauer spectroscopy lo the investigation of the chemical structure of solutions.
Solutions can be brought loa frozen stale and in this stale if they include Mössbauer-active atoms il is possible to record Mössbauer spectra. The process of freezing can be carricd out in a way lhat the ice formed preserves the most significant chemical features of the solutions. In that ease the Mössbauer method can serve as a rich source of information on the geometrical, chemical and magnetic structure of solulions.
The Mössbauer spectra of solulions and liquids can also be recorded al room temperature if they are diffunded in "thirsty glass" with a pore diameter of 4 nm. This recently developed measuring technique and ihe related principles are also discussed in this volume.
The second part of the book shows several applications of the Mössbauer technique for the study of hydration, solvation and hydrolysis of sails containing Mössbauer active elements. Some examples of the investigations of electron exchange reactions and coordination compound formation in solulions are also demonstrated. -
The glasses can be considered as frozen solulions and the Mössbauer study of ihese kinds of materials are also discussed.
This book will be most useful for experts dealing with solution and glass structures who would apply Mössbauer spectrum as a method. It is also recommended lo those dealing with chemical and physical research who are ready to extend their method in these fields. Vissza